South Texas - Wilcox Hybrid Formulation
 

The Wilcox Sand is an Eocene era deposit which is the main reservoir in a series of producing fields along the southern coastal region of Texas.
Ranging in depth from 9,000 to 13,000 ft the Wilcox is a tight, poorly consolidated, fine grained sand which has seen numerous drilling and completion techniques since the middle of the 20th century. Thought to contain in excess of 600 BCF of gas the Wilcox remains a major development target for operators in South Texas.

Additives


 
Product Name Additive Purpose Concentration U.S. MSDS
BA-20™ Organic Acid Acid used to adjust the pH of the base fluid 0.1 - 0.5 gal/1000 gal
BA-40L™ Buffer Helps to adjust the pH of the base fluid 0.75 gal/1000 gal
BE-6™ Biocide Prevents or limits growth of bacteria that can cause formation of hydrogen sulfide and can physically plug flow of oil and gas into the well 0.15 lbs/1000 gal
CL-31™ Crosslink Enhancer A non-delayed crosslinker for the gelling agent 0.25 - 0.75 gal/1000 gal
CL-37™ Crosslink Agent A delayed crosslinker for the gelling agent 0.25 gal/1000 gal
Gel-Sta L™ Gel Stabilizer Helps system maintain viscosity 9 gal/1000 gal
Losurf-300D™ Surfactant Aids in recovery of water used during frac 0.5 - 3 gal/1000 gal
LP-65™ Scale Inhibitor Prevents build up of certain materials (i.e. scale) on sides of the well casing and the surface equipment 0.25 - 10 gal/1000 gal
Premium Plus 20/40 mesh Proppant (Bauxite) Holds open fracture to allow oil and gas to flow to well 1 - 8 lbs/gal
SP Breaker Breaker Agent used to degrade viscosity 1 - 2 lbs/1000 gal
Vicon NF™ Breaker Agent used to degrade viscosity 1 - 10 gal/1000 gal
Water 4% KCl Base fluid creates fractures and carries proppant, also can be present in some additives N/A Supplied by Customer
WG-18™ Gelling Agent (CMHPG) Gelling agent for developing viscosity 20 - 45 lbs/1000 gal


 

Overall Percentage



Constituents

Constituents are the individual components used to form the additives described above.

In the table below, we identify these associated components, disclose their specific Chemical Abstracts Service (CAS) identification numbers, and list several prominent common uses for each.

Constituent Name
A discrete chemical with its own specific name or identity that is contained in an additive or chemical product.
Generic Name
Term most commonly used to describe the broad family of chemicals or substances.
CAS Number
Chemical classification principles used by the Chemical Abstracts Service (CAS), a division of the American Chemical Society. Descriptions of chemicals are listed by CAS number.
Common Use
Common applications of the material that may be used in the home or on the job in various substances.
Hazard as Appears on MSDS
Indicates a hazardous constituent as defined on a Material Safety Data Sheet (MSDS)
U.S. MSDS
Material Safety Data Sheet
Constituent Name Generic Name CAS Number Common Use Hazardous as Appears on MSDS
1,2,4 Trimethylbenzene Aromatic hydrocarbon 95-63-6 Paint, Mold Making Kit (Arts and Crafts) Yes
2-Bromo-2-nitro-1,3-propanediol Bronopol 52-51-7 Anti-Bacterial Soap, Skin Cleansing (Wipes), Hand Wash and Body Shampoo Yes
Acetic Acid Organic Acid 64-19-7 Processed Fruit, Cheese, Meat and Poultry Yes
Aluminum Oxide Metal Oxide 1344-28-1 Stone Polishing Powder, Aquarium Water Treatment, Ceramics Cleaner Yes
Aluminum Silicate Silicate 1304-76-7 Powdered Milk Anti-Caking Food Additive, Home and Commercial Fire Resistant Cement No
Ammonium Acetate Organic Salt 631-61-8 Static Guard, Soups and Broths Yes
Ammonium Chloride Inorganic Salt 12125-02-9 Hand Wash, Shampoo, Breakfast Cereal Yes
Carboxymethylhydroxypropyl guar Polysaccharide * Cosmetic Ingredient No
Chlorous Acid, Sodium Salt Inorganic Salt 7758-19-2 Food Additive Yes
Crystalline Silica, Cristobalite Silica 14464-46-1 Textured Foundation for Painting, Interior Paint Yes
Ethanol Alcohol 64-17-5 Ginseng, Deodorizer, Dish Soap, Cologne, Makeup (Mascara), Mouthwash Yes
Formaldehyde Aldehyde 50-00-0 Liquid Detergent, School Glue, Hand Soap No
Glycerin Glycerin 56-81-5 Laundry Stain Remover, Antimicrobial Soap, Toothpaste, Lipstick Yes
Heavy Aromatic Petroleum Naphtha Hydrocarbon-Petroleum Distillate 64742-94-5 Industrial Cleaning Solution, Tire Repair, Agricultural Insecticide Yes
Iron Oxide Metal Oxide 1309-37-1 Paint, Blush Makeup, Makeup Base, Eye Liner, Yogurts and Fermented Milk Products, Jams, Jellies and Marmalades Yes
Mullite Aluminum Silicate 1302-93-8 Industrial Fibrous Insulation Coating, Industrial Mortar No
Naphthalene Polycyclic Aromatic Hydrocarbon 91-20-3 Mothballs, Agricultural Insecticide, Heating Fuel Oil Yes
Oxyalkylated Phenolic Resin Oxyalkylated Phenolic Resin * No Common Product Uses Identified No
Oxyalkylated Phenolic Resin Oxyalkylated Phenolic Resin * No Common Product Uses Identified No
Phenol Phenol 108-95-2 Epoxy Adhesive, Floor Finish, Food Paper Packaging No
Phenol / Formaldehyde Resin Phenolic Resin 9003-35-4 Industrial Synthetic Wood Resin, Commercial Plywood, Industrial Adhesive Film No
Phosphonic Acid, [[(phosphonomethyl)imino]bis[2,1-ethanediylnitrilobis(methylene)]]tetrakis-, Ammonium Salt Organic Phosphonate 70714-66-8 Biocide in Industrial Water Treatment applications**, Industrial and Institutional Cleaning, Pulp and Paper Industry No
Poly(oxy-1,2-ethanediyl), alpha-(4-nonylphenyl)-omega-hydroxy-, Branched Alkyl Phenol Ethoxylate 127087-87-0 All Purpose Detergent, Industrial Hand Cleaner, Car Polish Yes
Potassium carbonate Carbonate 584-08-7 Cocoa and Chocolate Products, Infant and Young Children Foods, Cottage Cheese Yes
Potassium Hydroxide Hydroxide 1310-58-3 Anti-Bacterial Soap, Cocoa, Milk Products, Infant and Small Children Foods Yes
Potassium Metaborate Borate 13709-94-9 Industrial Photo Developing Agent, Soldering Flux Yes
Propanol Alcohol 71-23-8 Permanent Marker Yes
Silica, amorphous - fumed Silica 7631-86-9 Sealer No
Silicone Dioxide Silicone 60676-86-0 Deodorant, Mascara, Shaving Gel, Epoxy Molding, Food Additive Anti-Caking Agent for Cheese and Sugar No
Sodium Bicarbonate Bicarbonate 144-55-8 Baking Soda, Odor Absorber, Dishwashing Liquid, Canned Vegetables, Flour No
Sodium Chloride Inorganic Salt 7647-14-5 Concentrations greater than 1%: Food Grade Salt, Laundry Detergent, Ice Melting Product Yes
Sodium Persulfate Oxidant 7775-27-1 Hair Dye, Industrial Circuit Boards, Industrial Metal Cleaner Yes
Sodium Sulfate Sulfate 7757-82-6 Dishwasher Detergent, Laundry Detergent, Liquid Hand Soap, Toothpaste No
Sodium Sulfite Inorganic Salt 7757-83-7 Stain Remover, Hair Color, Beer Flavoring Additive No
Sodium Thiosulfate Sulfate 7772-98-7 Preservative, Stain Remover, Bleach and Chlorine Remover Yes
Titanium Dioxide Metal Oxide 13463-67-7 Interior Semi-Gloss Paint, Adhesive Putty, Eye Pencil, Makeup Concealer, Makeup Smoother, Cheese Yes
Triethanolamine Zirconate Zirconate 101033-44-7 Adhesives and printing Ink Yes
Water Water 7732-18-5 Water Present in Additives (Not Water used as Carrier Fluid) No

* In certain cases, a small percentage of constituents may be protected under existing agreements with suppliers and customers. In these situations, CAS numbers are not listed – but the constituent's listing as hazardous on the MSDS is, as well as other common uses when identified.
** Items identified in the "common uses" column were chosen in part because the constituents found in these products exist in roughly the same concentrations as would be found in fracturing materials at the wellhead. In some cases, however, concentrations present in consumer products are either not publicly available or in higher percentages than would be found at the wellsite.
 
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